Mild and Facile Synthesis of Multi-Functional RAFT Chain Transfer Agents
نویسندگان
چکیده
منابع مشابه
Facile RAFT synthesis of side-chain amino acids containing pH-responsive hyperbranched and star architectures†
This work reports the design and synthesis of amino acid-based hyperbranched polymers via the combination of self-condensing vinyl polymerization (SCVP) and reversible addition–fragmentation chain transfer (RAFT) polymerization from tert-butyl carbamate (Boc)-L-valine acryloyloxyethyl ester (Boc-Val-HEA) and S-(4-vinyl)benzyl S’-butyltrithiocarbonate (VBBT) with variable degrees of branching (D...
متن کاملFacile RAFT synthesis of side-chain amino acids containing pH-responsive hyperbranched and star architectures†
This work reports the design and synthesis of amino acid-based hyperbranched polymers via the combination of self-condensing vinyl polymerization (SCVP) and reversible addition–fragmentation chain transfer (RAFT) polymerization from tert-butyl carbamate (Boc)-L-valine acryloyloxyethyl ester (Boc-Val-HEA) and S-(4-vinyl)benzyl S’-butyltrithiocarbonate (VBBT) with variable degrees of branching (D...
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Novel cysteine and glutathione-based chain transfer agents were synthesized and successfully applied to the straightforward synthesis of well-defined conjugates via a RAFT process.
متن کاملsingle-step synthesis of multi-component spirobarbiturates using ionic liquids and synthesis of substituted pyridine filled with catalysts supported on solid substrate
in this thesis, a better reaction conditions for the synthesis of spirobarbiturates catalyzed by task-specific ionic liquid (2-hydroxy-n-(2-hydroxyethyl)-n,n-dimethylethanaminium formate), calcium hypochlorite ca(ocl)2 or n-bromosuccinimide (nbs) in the presence of water at room temperature by ultrasonic technique is provided. the design and synthesis of spirocycles is a challenging task becaus...
15 صفحه اولSynthesis of Polymeric Nanoparticles by Reversible Addition-fragmentation Chain Transfer (raft) Polymerization in Co2-induced Miniemulsion
Implementation of controlled/living radical polymerization in miniemulsion (typically with oil droplet diameter of 20-500 nm) for synthesis of well-defined, polymeric nanoparticles is of particular interest as miniemulsions possess the inherent advantage that ideally each monomer droplet is transformed into a polymer particles(Zetterlund et al., 2008). However, the high energy requirement for m...
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ژورنال
عنوان ژورنال: Polymers
سال: 2009
ISSN: 2073-4360
DOI: 10.3390/polym1010003